Tuesday, April 10, 2012

Bead VSM of methane, ammonium, water, and hydrogen fluoride

There is no doubt that tetravalent molecules such as methane occupy an important place in the chemical bond theory.
In 1865, German chemist August Wilhelm von Hofmann made the first stick-and-ball molecular models of methane in lecture at the Royal Institution of Great Britain. It is planar!

Then, 1872, van't Hoff, then a graduate student, learned of a possible tetrahedral arrangement of the valence bonds of carbon, proposed by the Russian chemist Alexander Butlerov in 1862. He later made a set of 3-D paper models of tetrahedral molecules.

Following Prof. H. Bent's recipes, Qing Pang (龐晴) of TFGH (北一女) made several bead valence sphere models (bead VSM) for tetravalent molecules with the formula AXnEm, where n+m=4, n is the number of bond electron pairs and m is the number of lone electron pairs. Here she didn't use the Windsor's knot to end the Nylon thread, instead she used simply tiny beads to cap the terminal beads of this kind of tree-like structures. Also, she use blue beads to represent bond electron pairs and yellow beads long electron pairs. You can see bead model exactly realizes the valence sphere model of Bent. I will show other bead VSM (made by Qing Pang) of molecules with several centers later.

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